Elsevier

Journal of Fluorine Chemistry

Thermodynamic properties and solubilityof potassium fluoride in aqueous solutions at diverse temperatures

Highlights

The experimental and calculated solubilities of potassium fluoride in aqueous solution were investigated.

The solubilities were determined at various temperatures from 298.xv–353.15K.

The water activities were carried out from dilution to saturation using the hygrometric method.

On the basis of the ion interaction model, the new parameters were evaluated.

The related backdrop were determined at different temperatures.

Abstract

The experimental and calculated solubilities of potassium fluoride in aqueous solutions were investigated at various temperatures. The experimental solubility of KF in aqueous solutions was determined up to mmax = 17.50 to 25.80 mol kg−one respectively from 298.15 to 353.15 K. The calculated solubility requires the thermodynamic backdrop of the binary organization based on the water activity measurements. Accordingly, the water activity of KF aqueous solutions were measured from diluted to the saturated solutions, using the hygrometric method at different temperatures. The related thermodynamic backdrop of KF(aq) were evaluated by the development of ion interaction model. The new binary parameters (β(0) (G,F), β(1) (K,F) , and Cφ (KF) ) were determined at diverse temperatures and used to evaluate the solute activity and the osmotic coefficients ranging from 298.15 to 353.15 Thou. The solubility product of KF(s) (given in 50 northward Grand southward p ° ) and the standard molar Gibbs energies of dissolution Δ Yard d i s s ° were as well given at different temperatures.

Keywords

Solubility

Water activeness

Solubility product

Potassium fluoride

Ion interaction model

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